Adobe TV (Free) - http://tv.adobe.com/product/dreamweaver/
Lynda.com (Subscription) - www.lynda.com
Adobe Developer Connection (Free) - http://www.adobe.com/devnet/dreamweaver.html
Devnet Article on creating your 1st website with DW (Free) - http://www.adobe.com/devnet/dreamweaver/articles/first_website_pt1.htm l
Video2Brain (Some free, some paid) - http://www.video2brain.com/en/dreamweaver
All the best!
If you want to design a website using Dreamweaver you can visit the link
And there will be related websites available.You can also watch Video Tutorials there.
Please understand that you will get much more benefit from studying HTML and CSS at this point, then you will studying DW. The more you know about the former, the flatter you will find DW's learning curve.
YOu can find many great tutorials very easy to follow at http://www.helpvid.net/tutorials/dreamweaver/dreamweaver.html