So I start editing all pic's in LR, then I want to do work in PS CS6. When I say edit in PS CS6 it skips RAW and go's right to PS. How do I get to RAW from PS screen?
You could choose Edit In>Open as Smart Object in Photoshop.
Then if you want to open camera raw after the file is in photoshop, double click on Layer thumbnail in the layers panel.
Is that part of the LR PS handling? It's new on me, although it is also moot now we have Camera RAW as a filter in PS CC