Once you build a site in Dreamweaver can you import it into Word press?
No - that's not how Wordpress works. To create a site in Wordpress, you need to select a theme from the universe of WP themes and customize it to look/perform as your PSD file. You can certainly export graphic elements from your PSD to use in the customized theme, but there is no way to build a page in DW and then import that page into Wordpress.
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You can't import PSD to Dreamweaver, but you can slice psd and then save for web, and then you will have an HTML file with site design, that can edit in Dreamweaver as you like if you expert with it only.
Also once we build site in Dreamweaver that can't directly import to WordPress, its can do a WordPress expert only.
HTML Developer psddesigntohtml.com