That should work okay, just install it in trial mode.
I'm moving this thread over to our download/installation forum.
For general Creative Cloud Membership questions, here is the FAQ link:
The IT department at my place of work installed CS6 Master Collection from a boxed software copy onto my machine (new Mac laptop, no previous Adobe software installed) as a trial.
At home, when I opened Photoshop (and after requesting a Java update, which was quick to install) it prompted me to enter my Adobe ID, which I has used to buy Creative Cloud Membership.
Now, all the programs seem to open and be working fine! Installing the software was a great time saver.