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You don't day how the system is set up on those two drives (I would but the OS and your applications on the ssd, myself) or how much RAM is on the video card, but the only thing I would say you might want to add is a dedicated scratch drive. The processor and RAM can certainly handle the load, and even the low end 1GB model onteh vido card should be adequate for ID, Photoshop, Illustrator and Acrobat. I don't do video or 3D, so I can't comment on them, but I suspect they would benefit from more memory on the video card.
The OS and apps will run on SSD. How big sholud the scratch drive be? Should it be a ssd or two discs in raid0?
I believe the rule of thumb for scratch disk is 4 times the size of the largest file you work on, but you'll have a lot of trouble finding anything that small anymore.
My system is a bit over a year old now and I didn't spend money on SSDs because people I trust said at the time they weren't really ready for prime time. I'm using a 300 GB SATA II drive, which is vastly too large from just a space consideration, but it was relatively inexpensinve and extra space doesn't count againt it. An SSD would probably be faster, but I'm not convinced it would make enough difference to justify the added expense unless you are really a power user in Photoshop. Same goes for RAID, but if you want to hear all the arguments, ask over in the Photoshop forum.