I am using PS CS6 in OS10.9.2
I use two monitors, one primarly for tools. I have saved the workspace set up I want but everytime I click on another application when I come back to PS the windows are all pilled up in the larger monitor. I have to either move one of them back to the other monitor or select the workspace to get them to return to the saved set up.
Is there a way to keep this from happening?
I think this is a side effect of the way Apple changed multiple monitor handling in 10.9.2. See if this helps: Open System Preferences, click Mission Control, and deselect "Displays have separate Spaces". You'll have to log out and back in for the change to take effect.