As soon as I run Photoshop 2014 for the first time, it bombs without error code but saying that it has been forwarded to tech support. I have Photoshop CS6 installed as well as Photoshop CC. Now even CC doesn't connect to photoshop from Bridge
It's been known to fail to run on a Game Boy.
Not trying to run it on a Nintendo? What DO you have, then? Mac or PC? OS version? Knowing this information someone might be able to ask you more specific questions, such as "what's in your error log that might identify what bombed".
Windows 8 on a PC
OK, then. Please look in your Windows Application event log. There should be information there describing the failure, time-stamped with the time of the failure. Most specifically, you're interested in what module failed.
PCs sometimes need display driver updates. What video card model and display driver version do you have?