I have ps5 and bridge on my laptop and would like to down load ps5 on my new desk top, can I have x2 PS 5 (laptop and desktop)?
I assume you mean Photoshop CS5, and not the ancient Photoshop 5 which is well over a decade old.
The license is for one user and two computers that will not be used simultaneously, so your scenario fits.
Just keep in mind that licenses for CS5 were platform specific, so either two Macs or two PC boxes.