Hi,i have the exact same problem.I cannot see the plan i am in under the order history,i did not receive any emails related to the purchase,but i got charged for it already.Also,i have downloaded photoshop once and it still says that the app is under trial.I did not receive anything related to the serial number whatsoever.
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There is no serial numbers for Creative Cloud products,
Sign out from Creative Cloud App and sign in back once
If trial warning is still appearing, then check your hosts file entries once