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Can you copy the new catalog file to the any other location like desktop. Try opening the catalog from there and let me know if this helps.
Yes, that worked THANKS!. I currently keep my catalog on an external hard drive. I just opened it from my desktop which is great to finish this session but is there any way to move it back to the hard drive?
yes you can copy it back to you hard drive , try to create a new folder and paste the catalog file in there. If the same issue occurs again, its a permission issue with the hard disk. Somehow Lightroom is not able to create the temp files at the time of the launch of the catalog
Okay I will try it after I finish these photos Thanks