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The presets would automatically migrate to Lightroom CC once you will upgrade your Lightroom 5 Catalog to CC version, if they are compatible with Lightroom CC.
They would be available in their designated modules, like develop presets should be under the Presets panel in Develop module after upgrade to Lightroom CC.
If you are installing CC on the same machine LR 5 is installed on all the presets should be carried over. All User Presets are stored with the standard presets in a subfolder named User Presets for all modules and actions under your UserName folder (in a slightly different place, path, for Windows or Mac). CC will update the standard Presets, if there are any, and should load your presets when LR is started.
Or if you have an option checked it might store them in the actual catalog file. As long as you use the same catalog, LR CC will copy the LR 5 catalog and convert that copy to a LR CC catalog, they should all load the first time LR is started.