Can you elaborate on what this application is going to do, and which platforms you are looking to support? This is a very open question, and there are possibly many ways to do this, including using various types of WebRTC. More information would be helpful.
Platforms : Android, iOS
I want to create a chat application with rooms having voice and video capabilities.
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The best way to do this is to look at the various WebRTC plugins that the community has developed and see if any of those would meet your current needs. Since WebRTC features are browser-based, and since PhoneGap and Cordova either use the existing browser on the device, or a third party browser like Crosswalk to display HTML/JS, you will most likely need to investigate some of these plugins. Unfortunately, I don't have a plugin that I can recommend at this time, however, Crosswalk is definitely worth looking at.