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Next to Post Photos to, you need to select an album or Timeline Photos.
Finally, I figured it out:
You need to have an album (at least one), to be able to upload picture(s) to Facebook from Lightroom CC.
That’s why, I just saw “nothing” after “Post photos to “ .. and the up/down arrows…
Would have been nice, if LR CC in the upload pop up had a short message about this, when no albums are available, like “No albums available”, instead of no text…
If you use Lightroom Mobile, you can of course upload to a post, as normal…