I am also having the same problem. For me the picture begins to print but basically looks like black and white clouds. I noticed a couple times when I would hit the print button Photoshop would crash. I should mention I am printing 13 x 19 pics using photoshop with canon plug in. Adobe has a page that try to resolve printing issues. One is to go into photoshop preferences and add more ram. I noticed the pixma 100 has some some software and driver updates. I am going to try that. I think my problem is somehow in the network. Hope you solve it!
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I tried everything with this exact same issue and what worked was to flatten the image before printing. I was using a photo-filter adjustment layer on a 13x13 image when the crash happened and I went through the whole process of updating OS, software, network connections, drivers, allocating more ram.... it took forever and I'm glad I did it but it still crashed as soon as I tried to print the image with the adjustment layer. Flattened it and *bingo*, we were in business. Fingers crossed that the issue actually gets fixed soon.... also haven't tried yet with a larger image. Don't forget to "un-flatten" the image before closing the file if you want to save the adjustment layer!