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Successful low key lighting is contingent on the original image but two options to explore with the appropriate image are the sliders in Image > Adjustments > Shadow/Highlights and some of the filters in Image > Adjustments > Color Lookup.
Thanks,appreciate it. I dont think this will work, this is an existing image and I tried this but not achieving that effect.This is actually an existing image, I was not aiming for lowkey, but I happened upon that option PSE11 that was an actual option. The sample picture was a lighter one like mine but was beautifully transformed to low key. I only have PSSE 10 and then upgraded to this whole Cloud program but that option is nowhere to be found.