I forgot to tell that I have this problem between all Adobe CC apps on Windows (After Effects is even worst in this kind of problem).
Using the same example as before; with this key, the primary character is comma and the secondary is semicolon. The comma is is already used as you can see in your screenshot for the grid.
As an extra, I would like to still using the default shortcuts because is already in my reflexes and I would need to be changing again and again between Windows and Mac the shortcut profile everytime 'cause Adobe CC sync everything, including the shortcuts.
This kind of problem started when I update to Windows 10 in my PC only.
Thanks for your answer with screenshot.
That seems too involved. Try going to your CC Desktop app > Preferences and change the language to Spanish.
When you go back to the main screen, Photoshop should then have an install button, which should drop the Spanish language pack into your PS program folder under Locales. The Spanish keyboard shortcut file should be there. Copy it into My Documents and use Edit > Keyboard Shortcuts to import the file in for your English version.