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Read Cloud takes over https://forums.adobe.com/thread/2089127 for some ideas (see reply #1)
-includes information on how to stop the update manager and/or Cloud from running at Windows startup
To Cancel a subscription https://helpx.adobe.com/creative-cloud/help/cancel-membership.html
-or reply #1 in https://forums.adobe.com/thread/2023066 - includes Chat link
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You also need to get the Creative Cloud stuff off your computer: this isn't related to whether the account is active. There isn't a Photoshop 6.5 by the way.