are you an administrator on your system ? From your translation, looks like CC Libraries have difficulties accessing your folder.
Hallo yenaphe, I started it last time as administrator, same problem.
Loud thinking: Other directories like Cache work, so it´s perhaps because of rights of the internet-Connection to the program to the folder oder so? Well, the images seem to be somewhere on my computer, because I can edit them through Premiere in Photoshop for example.
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I don't see why this is happening.
I would recommend getting in touch with Adobe Support, looks like a very specific error I've never heard about.