There is a lot of stuff around you could have a look at. You could try:
1. http://muvipix.com/products.php?subcat_id=6 (some free, some demand a subscription), or of course
and, of course, a Google search or a search on this forum, and you'll find enough helpful material to turn you into an expert.
When I started using the program, I learned a lot from this book: "Premiere Elements 2.0 in a snap". Still available at Amazon.
Although we're at Premiere Elements 7.0 now, it is still (in my opnion) the best book around for beginners.
Enjoy the program!
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Easily the best tutorials I have found yet on all Adobe products and more.