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Nope, doesn't work this way. For shape layers you have to twirl open the shape hierarchy in the timeline and simply delete the fill.
Thank you kindly
Thanks! That helped
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if you want the fill to be empty just click on the fill name and you will be presented with more options:
you can also alt+click on the fill color to change between different modes.
if you do create a using the pen tool or the parametric tool, you will still get a fill in the shape group, but its visibility will be toggled off.